Failure Processes in Embedded Monolayer Graphene under Axial Compression
Charalampos Androulidakis, Emmanuel N. Koukaras, Otakar Frank, Georgia Tsoukleri, Dimitris Sfyris, John Parthenios, Nicola Pugno, Konstantinos Papagelis, Kostya S. Novoselov & Costas Galiotis. Scientific Reports
DOI: 10.1038/srep05271
Exfoliated monolayer graphene flakes were embedded in a polymer matrix and loaded under axial compression. By monitoring the shifts of the 2D Raman phonons of rectangular flakes of various sizes under load, the critical strain to failure was determined. Prior to loading care was taken for the examined area of the flake to be free of residual stresses. The critical strain values for first failure were found to be independent of flake size at a mean value of –0.60% corresponding to a yield stress up to -6 GPa.
By combining Euler mechanics with a Winkler approach, we show that unlike buckling in air, the presence of the polymer constraint results in graphene buckling at a fixed value of strain with an estimated wrinkle wavelength of the order of 1–2 nm. These results were compared with DFT computations performed on analogue coronene/PMMA oligomers and a reasonable agreement was obtained.